Oxygen out, sulfur in: The alkali metal sulfidotungstates K <sub>2</sub> [WS <sub>4</sub> ] and novel Na <sub>2</sub> [WS <sub>4</sub> ] ⋅ 4 H <sub>2</sub> O

نویسندگان

چکیده

An attempt to synthesize a holmium sulfidotungstate using potassium polysulfides as reactive flux resulted in orange single crystals of K2[WS4], isotypic K2[MoS4] (orthorhombic; Pnma; a=935.10(3), b=694.22(2), c=1221.85(4) pm; Z=4). A similar obtain neodymium with sodium polysulfide yielded violet substance, which underwent hydrolysis yielding orange-yellow Na2[WS4] ⋅ 4 H2O (monoclinic, C2/c, a=1098.08(4), b=904.46(3), c=1144.27(4) pm, β=101.577(3)°, Further attempts these products deliberately phase materials only proved be successful for K2[WS4] but not H2O. Both compounds contain non-condensed [WS4]2− tetrahedra, surround the alkali metal cations coordination numbers nine and eight K2[WS4]. In H2O, are coordinated by two sulfide anions plus four water molecules, resulting number six. Besides crystal structure determination, infrared Raman spectra were collected optical band gap was determined.

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ژورنال

عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie

سال: 2022

ISSN: ['0044-2313', '1521-3749']

DOI: https://doi.org/10.1002/zaac.202200270